Dry Cell
A zinc-carbon battery with a paste electrolyte, used in torches and remotes.
Practise Acids, Bases & Electrochemistry All Acids, Bases & Electrochemistry topics
A zinc-carbon battery with a paste electrolyte, used in torches and remotes.
Practise Acids, Bases & Electrochemistry All Acids, Bases & Electrochemistry topics
The dry cell, usually a zinc-carbon battery, has a zinc can that serves as the anode and a graphite rod as the cathode, with a paste of manganese dioxide and ammonium chloride acting as the electrolyte and oxidizer. It delivers about 1.5 V and is inexpensive, which makes it convenient for low-drain devices such as torches and remote controls. As the cell is used the zinc corrodes, and the cell eventually runs down as the paste is depleted and reaction products build up. It is not rechargeable because the reactions cannot be reversed efficiently. It was the first widely used portable battery.
Key ideas: The Leclanche zinc-carbon cell: Zn anode (case), graphite rod cathode with MnO2, electrolyte paste of NH4Cl and ZnCl2. Anode: Zn giving Zn2+ + 2e-. Cathode: 2MnO2 + 2NH4+ + 2e- giving Mn2O3 + 2NH3 + H2O. Voltage is about 1.5 V and it declines gradually under load.
Common mistakes and connections: Mistakes: calling it a wet cell or rechargeable. Zinc case thins and can leak. Called dry because the electrolyte is a paste, not because there is no water. The cell is primary (not rechargeable) and has lower capacity than alkaline types, especially under high drain. Connected to galvanic cell concepts.
In a zinc-carbon dry cell the zinc can is the anode and the graphite rod carries electrons from MnO2 reduction; it gives about 1.5 V. The interactive lesson shows this as a live animation or chart.
The overall reaction is Zn + 2MnO2 + 2NH4+ -> Zn2+ + Mn2O3 + 2NH3 + H2O.
A zinc-carbon battery with a paste electrolyte, used in torches and remotes.
Dry Cell is a beginner topic in Acids, Bases & Electrochemistry. It needs no earlier chemistry lessons and is a good starting point.
Study these earlier topics in Acids, Bases & Electrochemistry first: Electrorefining, Hall-Heroult Process, Chlor-Alkali Process.
The next topics in Acids, Bases & Electrochemistry are Alkaline Battery and Lead-Acid Battery.
Yes. The interactive lesson includes a self-check question on Dry Cell, and the Acids, Bases & Electrochemistry quiz draws on every topic in this area.
Dry Cell is topic 68 of 105 in Acids, Bases & Electrochemistry.