Percent Composition
The mass percentage of each element in a compound.
Practise Analytical, Lab & Spectroscopy All Analytical, Lab & Spectroscopy topics
The mass percentage of each element in a compound.
Practise Analytical, Lab & Spectroscopy All Analytical, Lab & Spectroscopy topics
Percent composition gives the mass percentage of each element in a compound, found by dividing the total mass of that element in one mole of the compound by the molar mass of the compound and multiplying by 100. The percentages of all elements must sum to 100 percent, which serves as a check on the calculation. Chemists determine percent composition experimentally from combustion or elemental analysis, then use it to confirm the identity of a compound. It is also the starting point for deducing an empirical formula, because the percentages can be converted into moles of each element. Percent composition is independent of sample size, so it characterizes a pure compound regardless of how much is taken.
Key ideas: Mass percent of element = (n x atomic mass)/(molar mass) x 100, where n is the number of atoms in the formula. Check that percentages add to 100 within rounding. For hydrates, treat water as part of the formula: in CuSO4.5H2O the water is 90.08/249.7 = 36.1 percent. Experimental percentages are compared with calculated ones to confirm purity.
Common mistakes and connections: Students use atomic number instead of atomic mass, forget to multiply by the subscript, or divide by the wrong total. Another slip is using percent composition of a mixture as if it were a compound. Percentages from combustion analysis are often given for C, H and N with oxygen found by difference. Leads directly into empirical formula problems.
In water, 2.016 g of hydrogen and 16.00 g of oxygen per 18.02 g give 11.2 percent H and 88.8 percent O, which must total 100 percent. The interactive lesson shows this as a live animation or chart.
Water (18.02 g/mol) contains 2.016/18.02 = 11.2 percent hydrogen and 88.8 percent oxygen.
The mass percentage of each element in a compound.
Percent Composition is a beginner topic in Analytical, Lab & Spectroscopy. It needs no earlier chemistry lessons and is a good starting point.
Study these earlier topics in Analytical, Lab & Spectroscopy first: Scientific Notation, Dimensional Analysis, Density.
The next topics in Analytical, Lab & Spectroscopy are Empirical Formula and Molecular Formula.
Yes. The interactive lesson includes a self-check question on Percent Composition, and the Analytical, Lab & Spectroscopy quiz draws on every topic in this area.
Percent Composition is topic 10 of 99 in Analytical, Lab & Spectroscopy.