Fats and Oils
Triglycerides of glycerol and fatty acids, saturated or unsaturated.
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Triglycerides of glycerol and fatty acids, saturated or unsaturated.
Practise Biochemistry, Environment & Industry All Biochemistry, Environment & Industry topics
Fats and oils are triglycerides, esters formed when glycerol reacts with three fatty acids and releases water. Fats are solid at room temperature because they contain mostly saturated fatty acids whose straight chains pack tightly, whereas oils are liquid because they contain more unsaturated acids with kinked cis double bonds. Triglycerides are an efficient energy store, providing about 9 kcal (about 37 kJ) per gram, more than twice the energy of carbohydrate or protein. They also insulate the body and cushion internal organs. Their carbon atoms are more reduced than those of sugars, which is why they store so much energy per gram.
Key ideas: Triglycerides: glycerol esterified with three fatty acids. Fats are solid at room temperature (mostly saturated), oils are liquid (more unsaturated). Saponification with NaOH gives glycerol plus soap. Saponification value measures average chain length (higher means shorter chains) and iodine value measures degree of unsaturation.
Common mistakes and connections: Students call fats and oils different compounds; they differ only in fatty acid makeup. Hydrolysis of an ester with base is irreversible, unlike acid hydrolysis. Rancidity comes from oxidation of double bonds or hydrolysis. Links to soap making, esters and energy storage (about 38 kJ per gram).
Energy yield per gram. Triglycerides store more than twice the energy of carbohydrate or protein because their carbon is more reduced. The interactive lesson shows this as a live animation or chart.
Butter is solid at room temperature while olive oil is liquid, reflecting their different fatty acid compositions.
Triglycerides of glycerol and fatty acids, saturated or unsaturated.
Fats and Oils is a beginner topic in Biochemistry, Environment & Industry. It needs no earlier chemistry lessons and is a good starting point.
Study these earlier topics in Biochemistry, Environment & Industry first: Cofactors and Coenzymes, Vitamins, Hormones.
The next topics in Biochemistry, Environment & Industry are Saturated and Unsaturated Fatty Acids and Trans Fats.
Yes. The interactive lesson includes a self-check question on Fats and Oils, and the Biochemistry, Environment & Industry quiz draws on every topic in this area.
Fats and Oils is topic 18 of 127 in Biochemistry, Environment & Industry.
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