Dyes and Pigments
Colored organic compounds with extended conjugated systems.
Colored organic compounds with extended conjugated systems.
Dyes and pigments are coloured organic compounds that absorb visible light because they have extended conjugated systems. The colour arises from chromophores, which are groups such as the azo group N=N or the quinone system, and it is intensified by auxochromes such as OH and NH2 that donate electrons. Dyes dissolve or bind to the material they colour, while pigments are insoluble and are dispersed in the material. Azo dyes form the largest class of synthetic dyes, and natural dyes such as indigo and alizarin are also important.
Key ideas: Dyes are soluble coloured compounds that bind to fabric; pigments are insoluble. Colour arises from a chromophore (azo N=N, nitro, quinoid) conjugated with auxochromes (-OH, -NH2) that deepen colour. More conjugation shifts absorption to longer wavelengths (bathochromic). Azo dyes (about 60 percent of dyes) form by diazonium coupling, e.g. methyl orange. Classes by use: direct, vat (indigo), mordant and disperse dyes.
Common mistakes and connections: Students confuse the colour seen with the colour absorbed; it is the complementary colour. Another error is saying auxochromes cause colour alone, when they only modify a chromophore. Links to diazonium salts, conjugation, indicators and electronic transitions.
A dye absorbs one part of the visible spectrum and appears in the complementary colour; extended conjugation shifts absorption to longer wavelengths. The interactive lesson shows this as a live animation or chart.
Methyl orange is an azo dye whose colour changes with pH, which is why it is used as an acid-base indicator.
Colored organic compounds with extended conjugated systems.
Dyes and Pigments is a intermediate topic in Organic Chemistry. It builds on the vocabulary of beginner topics in this area.
Study these earlier topics in Organic Chemistry first: Steroids, Pharmaceuticals, Aspirin Synthesis.
The next topics in Organic Chemistry are Petrochemicals and Qualitative Organic Tests.
Yes. The interactive lesson includes a self-check question on Dyes and Pigments, and the Organic Chemistry quiz draws on every topic in this area.
Dyes and Pigments is topic 128 of 148 in Organic Chemistry.